nigel.stanger / Digital_Repository
Transfer to URL with SHA Find file
Newer
Older
Digital_Repository / Misc / Mass downloads / UTas / 2793.html
Nigel Stanger on 7 May 2013 25 KB - Imported Misc directory.
Raw Blame History 
  1. <!DOCTYPE html PUBLIC "-//W3C//DTD XHTML 1.0 Transitional//EN"
  2. "http://www.w3.org/TR/xhtml1/DTD/xhtml1-transitional.dtd">
  3. <html>
  4.   <head>
  5.     <title>UTas ePrints - Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)</title>
  6.     <script type="text/javascript" src="http://eprints.utas.edu.au/javascript/auto.js"><!-- padder --></script>
  7.     <style type="text/css" media="screen">@import url(http://eprints.utas.edu.au/style/auto.css);</style>
  8.     <style type="text/css" media="print">@import url(http://eprints.utas.edu.au/style/print.css);</style>
  9.     <link rel="icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  10.     <link rel="shortcut icon" href="/images/eprints/favicon.ico" type="image/x-icon" />
  11.     <link rel="Top" href="http://eprints.utas.edu.au/" />
  12.     <link rel="Search" href="http://eprints.utas.edu.au/cgi/search" />
  13.     <meta content="Casado Lacabra, M.A." name="eprints.creators_name" />
  14. <meta content="Canty, A.J." name="eprints.creators_name" />
  15. <meta content="Lutz, M." name="eprints.creators_name" />
  16. <meta content="Patel, J." name="eprints.creators_name" />
  17. <meta content="Spek, A.L." name="eprints.creators_name" />
  18. <meta content="Sun, H." name="eprints.creators_name" />
  19. <meta content="van Koten, G." name="eprints.creators_name" />
  20. <meta content="" name="eprints.creators_id" />
  21. <meta content="Allan.Canty@utas.edu.au" name="eprints.creators_id" />
  22. <meta content="" name="eprints.creators_id" />
  23. <meta content="" name="eprints.creators_id" />
  24. <meta content="" name="eprints.creators_id" />
  25. <meta content="" name="eprints.creators_id" />
  26. <meta content="" name="eprints.creators_id" />
  27. <meta content="article" name="eprints.type" />
  28. <meta content="2008-01-03 22:19:52" name="eprints.datestamp" />
  29. <meta content="2008-01-08 15:30:00" name="eprints.lastmod" />
  30. <meta content="show" name="eprints.metadata_visibility" />
  31. <meta content="Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)" name="eprints.title" />
  32. <meta content="pub" name="eprints.ispublished" />
  33. <meta content="259901" name="eprints.subjects" />
  34. <meta content="restricted" name="eprints.full_text_status" />
  35. <meta content="Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures" name="eprints.keywords" />
  36. <meta content="The definitive version is available at http://www.sciencedirect.com
  37. " name="eprints.note" />
  38. <meta content="The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2." name="eprints.abstract" />
  39. <meta content="2002" name="eprints.date" />
  40. <meta content="published" name="eprints.date_type" />
  41. <meta content="Inorganica Chimica Acta" name="eprints.publication" />
  42. <meta content="327" name="eprints.volume" />
  43. <meta content="1" name="eprints.number" />
  44. <meta content="15-19" name="eprints.pagerange" />
  45. <meta content="10.1016/S0020-1693(01)00681-8" name="eprints.id_number" />
  46. <meta content="TRUE" name="eprints.refereed" />
  47. <meta content="0020-1693" name="eprints.issn" />
  48. <meta content="http://dx.doi.org/10.1016/S0020-1693(01)00681-8" name="eprints.official_url" />
  49. <meta content="
  50. [1] S. Sergi, V. Marsala, R. Pietropaolo, F. Faraone, J. Organomet.
  51. Chem. 23 (1970) 281.
  52. [2] J. Kuyper, R. van der Laan, F. Jeanneaus, K. Vrieze, Transition
  53. Met. Chem. 1 (1976) 199.
  54. [3] B.R. Steele, K. Vrieze, Transition Met. Chem. 2 (1977) 140.
  55. [4] R.J. Puddephatt, M.A. Thomson, J. Organomet. Chem. 238
  56. (1982) 231.
  57. [5] J.D. Scott, R.J. Puddephatt, Organometallics 2 (1983) 1643.
  58. [6] M. Lashanizadehgan, M. Rashidi, J.E. Hux, R.J. Puddephatt,
  59. S.S.M. Ling, J. Organomet. Chem. 269 (1984) 317.
  60. [7] D.P. Bancroft, F.A. Cotton, L.R. Falvello, W. Schwotzer, Inorg.
  61. Chem. 25 (1986) 764.
  62. [8] H. Tobita, H. Habazaki, H. Ogino, Bull. Chem. Soc. Jpn. 60
  63. (1987) 797.
  64. [9] N. Hadj-Bagheri, R.J. Puddephatt, Polyhedron 7 (1988) 2695.
  65. [10] G. Alibrandi, D. Minniti, L. Monsu` Scolari, R. Romeo, Inorg.
  66. Chem. 28 (1989) 1939.
  67. [11] M. Rashidi, Z. Fakhroeian, R.J. Puddephatt, J. Organomet.
  68. Chem. 406 (1990) 261.
  69. [12] K.C. Lo¨ vqvist, O.F. Wendt, J.G. Leipoldt, Acta Chem. Scand.
  70. 50 (1996) 1069.
  71. [13] P. Kapoor, V.Yu. Kukushkin, K. Lo¨ vqvist, A. Oskarsson, J.
  72. Organomet. Chem. 517 (1996) 71.
  73. [14] M. Rashidi, M. Hashemi, M. Khorasani-Motlagh, R.J. Puddephatt,
  74. Organometallics 19 (2000) 2751.
  75. [15] A.J. Canty, J. Patel, B.W. Skelton, A.H. White, J. Organomet.
  76. Chem. 599 (2000) 195.
  77. [16] M. Albrecht, G. Rodriguez, J. Schoenmaker, G. van Koten, Org.
  78. Lett. 22 (2000) 3461.
  79. [17] L. Johansson, M. Tilset, J.A. Labinger, J.E. Bercaw, J. Am.
  80. Chem. Soc. 122 (2000) 10846.
  81. [18] M. Albrecht, H.P. Dijkstra, G. van Koten, submitted for
  82. publication.
  83. [19] G.B. Kauffman, D.O. Cowan, Inorg. Synth. 6 (1960)
  84. 211.
  85. [20] P.T. Beurskens, G. Admiraal, G. Beurskens, W.P. Bosman, S.
  86. Garcia-Granda, R.O. Gould, J.M.M. Smits, C. Smykalla, The
  87. DIRDIF-97 Program System, Technical Report of the Crystallography
  88. Laboratory, University of Nijmegen, The Netherlands,
  89. 1997.
  90. [21] G.M. Sheldrick, SHELX-97: Program for Crystal Structure Refinement,
  91. University of Go¨ ttingen, Go¨ ttingen, Germany, 1997.
  92. [22] A.L. Spek, PLATON: A Multipurpose Crystallographic Tool,
  93. Utrecht University, The Netherlands, 2000.
  94. [23] Z. Otwinowski, W. Minor, in: C.W. Carter, R.M. Sweet (Eds.),
  95. Methods in Enzymology, Academic Press, New York, 1997, p.
  96. 307.
  97. [24] A.J.M. Duisenberg, J. Appl. Crystallogr. 25 (1992) 92.
  98. [25] A.J.M. Duisenberg, Thesis, Utrecht University, The Netherlands,
  99. 1998.
  100. [26] R. Herbst-Irmer, G.M. Sheldrick, Acta Crystallogr., Sect B 54
  101. (1998) 443." name="eprints.referencetext" />
  102. <meta content="Casado Lacabra, M.A. and Canty, A.J. and Lutz, M. and Patel, J. and Spek, A.L. and Sun, H. and van Koten, G. (2002) Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine). Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693" name="eprints.citation" />
  103. <meta content="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf" name="eprints.document_url" />
  104. <link rel="schema.DC" href="http://purl.org/DC/elements/1.0/" />
  105. <meta content="Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)" name="DC.title" />
  106. <meta content="Casado Lacabra, M.A." name="DC.creator" />
  107. <meta content="Canty, A.J." name="DC.creator" />
  108. <meta content="Lutz, M." name="DC.creator" />
  109. <meta content="Patel, J." name="DC.creator" />
  110. <meta content="Spek, A.L." name="DC.creator" />
  111. <meta content="Sun, H." name="DC.creator" />
  112. <meta content="van Koten, G." name="DC.creator" />
  113. <meta content="259901 Organometallic Chemistry" name="DC.subject" />
  114. <meta content="The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2." name="DC.description" />
  115. <meta content="2002" name="DC.date" />
  116. <meta content="Article" name="DC.type" />
  117. <meta content="PeerReviewed" name="DC.type" />
  118. <meta content="application/pdf" name="DC.format" />
  119. <meta content="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf" name="DC.identifier" />
  120. <meta content="http://dx.doi.org/10.1016/S0020-1693(01)00681-8" name="DC.relation" />
  121. <meta content="Casado Lacabra, M.A. and Canty, A.J. and Lutz, M. and Patel, J. and Spek, A.L. and Sun, H. and van Koten, G. (2002) Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine). Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693" name="DC.identifier" />
  122. <meta content="http://eprints.utas.edu.au/2793/" name="DC.relation" />
  123. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/BibTeX/epprod-eprint-2793.bib" title="BibTeX" type="text/plain" />
  124. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/ContextObject/epprod-eprint-2793.xml" title="OpenURL ContextObject" type="text/xml" />
  125. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/ContextObject::Dissertation/epprod-eprint-2793.xml" title="OpenURL Dissertation" type="text/xml" />
  126. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/ContextObject::Journal/epprod-eprint-2793.xml" title="OpenURL Journal" type="text/xml" />
  127. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/DC/epprod-eprint-2793.txt" title="Dublin Core" type="text/plain" />
  128. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/DIDL/epprod-eprint-2793.xml" title="DIDL" type="text/xml" />
  129. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/EndNote/epprod-eprint-2793.enw" title="EndNote" type="text/plain" />
  130. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/HTML/epprod-eprint-2793.html" title="HTML Citation" type="text/html; charset=utf-8" />
  131. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/METS/epprod-eprint-2793.xml" title="METS" type="text/xml" />
  132. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/MODS/epprod-eprint-2793.xml" title="MODS" type="text/xml" />
  133. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/RIS/epprod-eprint-2793.ris" title="Reference Manager" type="text/plain" />
  134. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/Refer/epprod-eprint-2793.refer" title="Refer" type="text/plain" />
  135. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/Simple/epprod-eprint-2793text" title="Simple Metadata" type="text/plain" />
  136. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/Text/epprod-eprint-2793.txt" title="ASCII Citation" type="text/plain; charset=utf-8" />
  137. <link rel="alternate" href="http://eprints.utas.edu.au/cgi/export/2793/XML/epprod-eprint-2793.xml" title="EP3 XML" type="text/xml" />
  138.  
  139.   </head>
  140.   <body bgcolor="#ffffff" text="#000000" onLoad="loadRoutine(); MM_preloadImages('images/eprints/ePrints_banner_r5_c5_f2.gif','images/eprints/ePrints_banner_r5_c7_f2.gif','images/eprints/ePrints_banner_r5_c8_f2.gif','images/eprints/ePrints_banner_r5_c9_f2.gif','images/eprints/ePrints_banner_r5_c10_f2.gif','images/eprints/ePrints_banner_r5_c11_f2.gif','images/eprints/ePrints_banner_r6_c4_f2.gif')">
  141.     
  142.     <div class="ep_noprint"><noscript><style type="text/css">@import url(http://eprints.utas.edu.au/style/nojs.css);</style></noscript></div>
  143.  
  144.  
  145.  
  146.  
  147. <table width="795" border="0" cellspacing="0" cellpadding="0">
  148.   <tr>
  149.     <td><script language="JavaScript1.2">mmLoadMenus();</script>
  150.       <table border="0" cellpadding="0" cellspacing="0" width="795">
  151.         <!-- fwtable fwsrc="eprints_banner_final2.png" fwbase="ePrints_banner.gif" fwstyle="Dreamweaver" fwdocid = "1249563342" fwnested="0" -->
  152.         <tr>
  153.           <td><img src="/images/eprints/spacer.gif" width="32" height="1" border="0" alt="" /></td>
  154.           <td><img src="/images/eprints/spacer.gif" width="104" height="1" border="0" alt="" /></td>
  155.           <td><img src="/images/eprints/spacer.gif" width="44" height="1" border="0" alt="" /></td>
  156.           <td><img src="/images/eprints/spacer.gif" width="105" height="1" border="0" alt="" /></td>
  157.           <td><img src="/images/eprints/spacer.gif" width="41" height="1" border="0" alt="" /></td>
  158.           <td><img src="/images/eprints/spacer.gif" width="16" height="1" border="0" alt="" /></td>
  159.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  160.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  161.           <td><img src="/images/eprints/spacer.gif" width="68" height="1" border="0" alt="" /></td>
  162.           <td><img src="/images/eprints/spacer.gif" width="82" height="1" border="0" alt="" /></td>
  163.           <td><img src="/images/eprints/spacer.gif" width="69" height="1" border="0" alt="" /></td>
  164.           <td><img src="/images/eprints/spacer.gif" width="98" height="1" border="0" alt="" /></td>
  165.           <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  166.         </tr>
  167.         <tr>
  168.           <td colspan="12"><img name="ePrints_banner_r1_c1" src="/images/eprints/ePrints_banner_r1_c1.gif" width="795" height="10" border="0" alt="" /></td>
  169.           <td><img src="/images/eprints/spacer.gif" width="1" height="10" border="0" alt="" /></td>
  170.         </tr>
  171.         <tr>
  172.           <td rowspan="6"><img name="ePrints_banner_r2_c1" src="/images/eprints/ePrints_banner_r2_c1.gif" width="32" height="118" border="0" alt="" /></td>
  173.           <td rowspan="5"><a href="http://www.utas.edu.au/"><img name="ePrints_banner_r2_c2" src="/images/eprints/ePrints_banner_r2_c2.gif" width="104" height="103" border="0" alt="" /></a></td>
  174.           <td colspan="10"><img name="ePrints_banner_r2_c3" src="/images/eprints/ePrints_banner_r2_c3.gif" width="659" height="41" border="0" alt="" /></td>
  175.           <td><img src="/images/eprints/spacer.gif" width="1" height="41" border="0" alt="" /></td>
  176.         </tr>
  177.         <tr>
  178.           <td colspan="3"><a href="http://eprints.utas.edu.au/"><img name="ePrints_banner_r3_c3" src="/images/eprints/ePrints_banner_r3_c3.gif" width="190" height="31" border="0" alt="" /></a></td>
  179.           <td rowspan="2" colspan="7"><img name="ePrints_banner_r3_c6" src="/images/eprints/ePrints_banner_r3_c6.gif" width="469" height="37" border="0" alt="" /></td>
  180.           <td><img src="/images/eprints/spacer.gif" width="1" height="31" border="0" alt="" /></td>
  181.         </tr>
  182.         <tr>
  183.           <td colspan="3"><img name="ePrints_banner_r4_c3" src="/images/eprints/ePrints_banner_r4_c3.gif" width="190" height="6" border="0" alt="" /></td>
  184.           <td><img src="/images/eprints/spacer.gif" width="1" height="6" border="0" alt="" /></td>
  185.         </tr>
  186.         <tr>
  187.           <td colspan="2"><img name="ePrints_banner_r5_c3" src="/images/eprints/ePrints_banner_r5_c3.gif" width="149" height="1" border="0" alt="" /></td>
  188.           <td rowspan="2" colspan="2"><a href="/information.html" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821132634_0,0,25,null,'ePrints_banner_r5_c5');MM_swapImage('ePrints_banner_r5_c5','','/images/eprints/ePrints_banner_r5_c5_f2.gif',1);"><img name="ePrints_banner_r5_c5" src="/images/eprints/ePrints_banner_r5_c5.gif" width="57" height="25" border="0" alt="About" /></a></td>
  189.           <td rowspan="2"><a href="/view/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133021_1,0,25,null,'ePrints_banner_r5_c7');MM_swapImage('ePrints_banner_r5_c7','','/images/eprints/ePrints_banner_r5_c7_f2.gif',1);"><img name="ePrints_banner_r5_c7" src="/images/eprints/ePrints_banner_r5_c7.gif" width="68" height="25" border="0" alt="Browse" /></a></td>
  190.           <td rowspan="2"><a href="/perl/search/simple" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133201_2,0,25,null,'ePrints_banner_r5_c8');MM_swapImage('ePrints_banner_r5_c8','','/images/eprints/ePrints_banner_r5_c8_f2.gif',1);"><img name="ePrints_banner_r5_c8" src="/images/eprints/ePrints_banner_r5_c8.gif" width="68" height="25" border="0" alt="Search" /></a></td>
  191.           <td rowspan="2"><a href="/perl/register" onMouseOut="MM_swapImgRestore();MM_startTimeout();" onMouseOver="MM_showMenu(window.mm_menu_1018171924_3,0,25,null,'ePrints_banner_r5_c9');MM_swapImage('ePrints_banner_r5_c9','','/images/eprints/ePrints_banner_r5_c9_f2.gif',1);"><img name="ePrints_banner_r5_c9" src="/images/eprints/ePrints_banner_r5_c9.gif" width="68" height="25" border="0" alt="register" /></a></td>
  192.           <td rowspan="2"><a href="/perl/users/home" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133422_4,0,25,null,'ePrints_banner_r5_c10');MM_swapImage('ePrints_banner_r5_c10','','/images/eprints/ePrints_banner_r5_c10_f2.gif',1);"><img name="ePrints_banner_r5_c10" src="/images/eprints/ePrints_banner_r5_c10.gif" width="82" height="25" border="0" alt="user area" /></a></td>
  193.           <td rowspan="2"><a href="/help/" onMouseOut="MM_swapImgRestore();MM_startTimeout()" onMouseOver="MM_showMenu(window.mm_menu_0821133514_5,0,25,null,'ePrints_banner_r5_c11');MM_swapImage('ePrints_banner_r5_c11','','/images/eprints/ePrints_banner_r5_c11_f2.gif',1);"><img name="ePrints_banner_r5_c11" src="/images/eprints/ePrints_banner_r5_c11.gif" width="69" height="25" border="0" alt="Help" /></a></td>
  194.           <td rowspan="3" colspan="4"><img name="ePrints_banner_r5_c12" src="/images/eprints/ePrints_banner_r5_c12.gif" width="98" height="40" border="0" alt="" /></td>
  195.           <td><img src="/images/eprints/spacer.gif" width="1" height="1" border="0" alt="" /></td>
  196.         </tr>
  197.         <tr>
  198.           <td rowspan="2"><img name="ePrints_banner_r6_c3" src="/images/eprints/ePrints_banner_r6_c3.gif" width="44" height="39" border="0" alt="ePrints home" /></td>
  199.           <td><a href="/" onMouseOut="MM_swapImgRestore()" onMouseOver="MM_swapImage('ePrints_banner_r6_c4','','/images/eprints/ePrints_banner_r6_c4_f2.gif',1);"><img name="ePrints_banner_r6_c4" src="/images/eprints/ePrints_banner_r6_c4.gif" width="105" height="24" border="0" alt="ePrints home" /></a></td>
  200.           <td><img src="/images/eprints/spacer.gif" width="1" height="24" border="0" alt="" /></td>
  201.         </tr>
  202.         <tr>
  203.           <td><img name="ePrints_banner_r7_c2" src="/images/eprints/ePrints_banner_r7_c2.gif" width="104" height="15" border="0" alt="" /></td>
  204.           <td colspan="8"><img name="ePrints_banner_r7_c4" src="/images/eprints/ePrints_banner_r7_c4.gif" width="517" height="15" border="0" alt="" /></td>
  205.           <td><img src="/images/eprints/spacer.gif" width="1" height="15" border="0" alt="" /></td>
  206.         </tr>
  207.       </table></td>
  208.   </tr>
  209.     <tr><td><table width="100%" style="font-size: 90%; border: solid 1px #ccc; padding: 3px"><tr>
  210.       <td align="left"><a href="http://eprints.utas.edu.au/cgi/users/home">Login</a> | <a href="http://eprints.utas.edu.au/cgi/register">Create Account</a></td>
  211.       <td align="right" style="white-space: nowrap">
  212.         <form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/search" style="display:inline">
  213.           <input class="ep_tm_searchbarbox" size="20" type="text" name="q" />
  214.           <input class="ep_tm_searchbarbutton" value="Search" type="submit" name="_action_search" />
  215.           <input type="hidden" name="_order" value="bytitle" />
  216.           <input type="hidden" name="basic_srchtype" value="ALL" />
  217.           <input type="hidden" name="_satisfyall" value="ALL" />
  218.         </form>
  219.       </td>
  220.     </tr></table></td></tr>
  221.   <tr>
  222.     <td class="toplinks"><!-- InstanceBeginEditable name="content" -->
  223.  
  224.  
  225. <div align="center">
  226.   
  227.   <table width="720" class="ep_tm_main"><tr><td align="left">
  228.     <h1 class="ep_tm_pagetitle">Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)</h1>
  229.     <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Casado Lacabra, M.A.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Lutz, M.</span> and <span class="person_name">Patel, J.</span> and <span class="person_name">Spek, A.L.</span> and <span class="person_name">Sun, H.</span> and <span class="person_name">van Koten, G.</span> (2002) <xhtml:em>Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine).</xhtml:em> Inorganica Chimica Acta, 327 (1). pp. 15-19. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2793/1/ICA327_2C_15.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />128Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3821" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0020-1693(01)00681-8">http://dx.doi.org/10.1016/S0020-1693(01)00681-8</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com&#13;
  230. </td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2793</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">04 Jan 2008 09:19</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2793;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2793">item control page</a></p>
  231.   </td></tr></table>
  232. </div>
  233.  
  234.  
  235.  
  236.     <!-- InstanceEndEditable --></td>
  237.   </tr>
  238.   <tr>
  239.     <td><!-- #BeginLibraryItem "/Library/footer_eprints.lbi" -->
  240.     <table width="795" border="0" align="left" cellpadding="0" class="footer">
  241.   <tr valign="top">
  242. <td colspan="2"><div align="center"><a href="http://www.utas.edu.au">UTAS home</a> | <a href="http://www.utas.edu.au/library/">Library home</a> | <a href="/">ePrints home</a> | <a href="/contact.html">contact</a> | <a href="/information.html">about</a> | <a href="/view/">browse</a> | <a href="/perl/search/simple">search</a> | <a href="/perl/register">register</a> | <a href="/perl/users/home">user area</a> | <a href="/help/">help</a></div><br /></td>
  243. </tr>
  244. <tr><td colspan="2"><p><img src="/images/eprints/footerline.gif" width="100%" height="4" /></p></td></tr>
  245.       <tr valign="top">
  246.         <td width="68%" class="footer">Authorised by the University Librarian<br />
  247. © University of Tasmania ABN 30 764 374 782<br />
  248.       <a href="http://www.utas.edu.au/cricos/">CRICOS Provider Code 00586B</a> | <a href="http://www.utas.edu.au/copyright/copyright_disclaimers.html">Copyright &amp; Disclaimers</a> | <a href="http://www.utas.edu.au/accessibility/index.html">Accessibility</a> | <a href="http://eprints.utas.edu.au/feedback/">Site Feedback</a>  </td>
  249.         <td width="32%"><div align="right">
  250.             <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><img src="http://www.utas.edu.au/shared/logos/unioftasstrip.gif" alt="University of Tasmania Home Page" width="260" height="16" border="0" align="right" /></a></p>
  251.             <p align="right" class="NoPrint"><a href="http://www.utas.edu.au/"><br />
  252.             </a></p>
  253.         </div></td>
  254.       </tr>
  255.       <tr valign="top">
  256.         <td><p>  </p></td>
  257.         <td><div align="right"><span class="NoPrint"><a href="http://www.eprints.org/software/"><img src="/images/eprintslogo.gif" alt="ePrints logo" width="77" height="29" border="0" align="bottom" /></a></span></div></td>
  258.       </tr>
  259.     </table>
  260.     <!-- #EndLibraryItem -->
  261.     <div align="center"></div></td>
  262.   </tr>
  263. </table>
  264.  
  265.   </body>
  266. </html>